钙钛矿型混合导体透氧膜用于CO2+高温分解反应研究.pdfVIP

钙钛矿型混合导体透氧膜用于CO 高温分解反应 2 * 张鹏 金万勤 范益群 徐南平 时钧 （南京工业大学膜科学技术研究所，江苏省材料化学工程重点实验室，江苏南京210009 ） 摘 要 SrCo0.4Fe0.5Zr0.1O3-δ (SCFZ)钙钛矿型混合导体透氧膜被用于二氧化碳高温分解反应，实验考察了在膜 反应器的吹扫气侧（吹扫气为CH 和Ar ）装填和不装填NiO/Al O 催化剂对二氧化碳分解反应效果的影响， 4 2 3 研究发现CO2 转化率和氧渗透通量都随着温度的升高而增加，在吹扫气侧装填催化剂时的CO2 转化率和氧 渗透通量要略高于没有装填催化剂时的情况。 关键词 钙钛矿氧化物 陶瓷膜 氧渗透 CO2 热分解 膜反应器 THE DECOMPOSITION OF CO IN A 2 OXYGEN-PERMEABLE MEMBRANE REACTOR ZHANG Peng, JIN Wanqin, FAN Yiqun, XU Nanping and SHI Jun (Membrane Science Technology Research Center, Key Laboratory of Material-oriented Chemical Engineering of Jiangsu Province, Nanjing University of Technology, Nanjing 210009, China) Abstract The perovskite-type mixed-conducting SrCo0.4Fe0.5Zr0.1O3-δ (SCFZ) membrane was used for the thermal decomposition of CO2 in a membrane reactor. The reaction performance of the SCFZ membrane reactor was investigated with and without NiO/Al O catalysts packed on the 2 3 side of CH sweep gas of the membrane. The CO conversion obviously higher than the expected 4 2 thermodynamic equilibrium value was achieved. The CO2 conversion and oxygen permeation flux increased with increase in temperature. The CO2 conversion and oxygen permeation flux in the presence of catalysts were higher than those without catalysts. Keywords perovskite-type membrane, the decomposition of CO2, syngas, oxygen permeation, membrane reactor 引 言 目前，CO2 的大量排放所产生的“温室效应”使得全球气候变暖，并且随着石油能源日 * 通讯联系人：徐南平Tel.: 025 Fax: 025-833