制备条件对吸附蓄热复合材料性能的影响研究.pdfVIP

C058 制备条件对吸附蓄热复合材料性能的影响* 吴会军 朱冬生 范忠雷 （华南理工大学传热强化与过程节能教育部重点实验室，广东广州 510640 ） 要：通过把CaCl2 介入到硅胶的纳米孔道内，制备出一种新型吸附蓄热复合材料。对复合材料 的吸附性能进行了实验测试，并对复合材料的蓄热性能进行了研究，分析了制备条件对复合材料 吸附和蓄热性能的影响。研究结果表明：在复合材料的制备过程中，增大溶液中CaCl2 的浓度， 可明显提高复合材料的吸附平衡量；浸泡 度对复合材料的影响较小；当浸泡时间达到 4h 时， 复合材料的吸附性能基本不变。这种新型复合材料的吸附平衡量最高可达 0.58kg/kg ，为硅胶的 3.6 倍，蓄热密度可高达 940kJ/kg ，而且在 80-110℃即可有效再生，是一种理想的蓄热材料，对 于提高能源的利用效率具有重要的意义。 关键词：蓄热 吸附 复合吸附材料 硅胶 中图分类号：TK02 Influence of preparing conditions on performance of composite adsorbent for thermal storage WU Huijun, ZHU Dongsheng and FAN Zhonglei (Key Laboratory of Enhanced Heat Transf er Energy Conservation of Ministry of Education, South China University of Technology, Guangzhou 510640, China ) Abstract A new kind of thermal storage composite adsorbent was prepared by implanting CaCl2 in the mesopores of silica gel. Experiments were carried out on the adsorption performance of new composite adsorbent. The influences of preparing conditions on adsorption performance were analyzed, and the thermal storage property was also studied. Experimental results show that high CaCl2 concentration increases the equilibrium adsorbed amount of composite adsorbent remarkably, while high immersing temperature increases that faintly. And the adsorbed amount remains constant when the immersing time is longer than 4h. The thermal storage density is up to 940kJ/kg, and the thermal storage composite can be efficiently regenerated at 80-110℃. This composite adsorbent is prior to increase the utilization efficiency of energy resource. Keywords thermal storage, adsorption, composite adsorbent, silica gel 引 言 * 基金项目：教育部优秀青年教师资助计划项目；高等学校博士学科点专项科研基金项目；广东省自 然科学基金 (011584) ；广州市科技计划项目；国家自然科学基金项目 作者简介：吴会军 1978 －），男，博士生，主要从事传热强化与节能、吸附技术和CFD 模拟的研究， wuhuij