六氯苯碱催化分解脱氯效果及影响因素研究 Study on base-catalyzed decomposition of hexachlorobenzene and influencing factors.pdfVIP
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六氯苯碱催化分解脱氯效果及影响因素研究 Study on base-catalyzed decomposition of hexachlorobenzene and influencing factors
China Science
中国环境科学2012,32(12):2213-2218 Environmental
六氯苯碱催化分解脱氯效果及影响因素研究
肖 叶1,蒋建国p,杨 勇2,黄泳锋1(1.清华大学环境学院,固体废物处理与环境安全教育部重点实验室,北京
100084;2.北京鼎实环境工程有限公司,北京100029)
摘要:采用自主设计开发的碱催化设备研究了碱催化分解技术∞cD)对六氯苯(HCB)脱氯的效果.考察了反应温度、氢氧化钠投加比例以
及不同催化剂对六氯苯去除效率、脱氯效率以及中间代谢产物的影响.提高反应温度和氢氧化钠投加比例能够有效提高六氯苯的脱氯解毒
剂时,在330C反应1h后,能够将六氯苯的脱氯效率由38.99%提高至77.51%.
关键词:六氯苯;碱催化分解技术(BCD);反应温度:催化剂
中图分类号:X705 文献标识码:A 文章编号:1000一6923(2012)12—2213一06
on of
hexaehlorobenzeneand factors.XIAO
Studybase-eatalyzeddecomposition influencing Ybl,JIANGJian-guo”,
YANG forSolidWasteTreatmentand of
Yon92,HUANGYong-fen91(1。KeyLaboratory Environment
of
Eduction,School
Environment,TsinghuaUniversity,BeUing100084,China;2.BeijingDingshi
Environmental
EngineeringCo.,Ltd.,Beijing100029,China).ChinaScience,2012,32(12):2213~2218
inan
Abstract:Base-catabrzed studied
decomposition(BCD)ofhexachlorobenzene(HCB)Was
reactor.Theeffectofreaction anddifferent theHCB
on removal
temperature.sodiumhydroxideproportion catalysts
and hasbeen HCB
efficiency,dechlorinationintermediates dechlorination
efficiency investigated.The
withthe ofreaction andsodium thesodium
improved increasing temperature hydroxideproportion.When
Was thereaction Was removal and
proportion1:5(HCB:sodium 360℃,the
hydroxide,m/m)andtemperature
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