PtPd-WC_C催化剂上的析氢反应.doc

第28卷专辑Ⅱ 武汉理工大学学报 Vot．28 Suppt。11 2006年11月 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY Nov．2006 PtPd．WC／C催化剂上的析氢反应 吴梅1一，沈培康1，魏子栋2，宋树芹1，聂 明1，2 (1．中山大学光电材料与技术国家重点实验室物理科学与技术学院，广州510275；2．重庆大学化学化工学院 ’ 重庆400044) 摘要：在制氩工业中发展廉价有鼓的电催化荆是十分关键的。耙Pd加入到Pt-W∽纳束晶杠中刺得 PtPd—WC／C电催化荆。并且对谊催化荆在酸性介质中的催化析氢性能进行了测试。结果显示PtPd-WC／C电催化 卉6比Pt．WC／C电催化剂的析氢活性有很大竹提高，在过电位为100mV时电流密度提高近200mA／em2。另外。电 解质浓度和温度对催化剂性能的影响也被进行研究。动力学研究表明：PtPd-WC／C电催化剂在高浓度H2S04溶 液中的过电位更低。SEM、XRD和TEM对PtPd．WC／C电催化卉4表征证明催化荆呈晶体状态和Pt、Pd、wC共存。 关键词：析氢反应；PtPd．WC／C电催化刺；瑗化鸪；燃料电池 中围分类号：TQ 116．2 文献标志码：A 文章编号：1671，4431(2006)专辑Ⅱ一0087．06 Hydrogen Evolution Reaction on PtPd-WC／C Electrocatalyst WU Meil，一，SHEN Pei．kan91，WEI Zi—don92，SONG Shu—qinl．Nil?,Min91·2 (1．State Key Laboratory of optodo：tron／e Materials and‰bg涵，Schoolof Physia and El】gineering，Sun Yat-scn University，Guan口hou 510275，Chim；2．School of Chendcal En#neerkg，Chongqing Univers时，Chongqing 400044，China) Ahstract：Successful development d【oW cost．effidem eloctrocata[ysts wil【be erucia[to the development of hydtogea production(or hydrogen evolution)technology．Here palladium(Pd)was adulterated into Pt on tungsten carbide nanocrystals，obtaining PtPd-WC／C eloetrocatalysts which were prepared by an intermittent microwave heating(IMH) method，and the composite eleetroeatalysta was tested for the hydrogen evolution reaction(HER)in the acidic media． The鹏IlItS showed a better performance of the HER on PtPd．WC／C electrocatalyst than that oxl Pt-WC／C electrceata— lyst．In addition。these effects on the cataiytic activity by changing environmental temperature and electrolyte concentra- tion were taken into account．Kinetic study showed that the HER on the PtPd-WC／C electrocatalyst gave higher exchange current dermity in It2S04 aolurion with high ooncentratlon．1eading to a lower overpotential and facile kinetics，XRD． SEM and TEM imago of PtPd-WC／C showed the crystalline features of Pt。Pd and tungsten carbides and indieated the coexistence of these componen