碱土金属对锆基钙钛矿材料负载钌催化剂氨合成性能的影响-催化学报.PDF

2013 Chinese Journal of Catalysis Vol. 34 No. 2 DOI : 10.3724/SP.J.1088.2013.20744 研究论文: 361–366 碱土金属对锆基钙钛矿材料负载钌催化剂氨合成性能的影响 ∗ , , , , , 350002 摘要: 采用柠檬酸络合法制备了含Ca, Sr和Ba 的锆基钙钛矿材料, 负载Ru后用于催化氨合成反应; 研究了碱土金属对催化剂织构性 能和载体材料表面碱性的影响, 并与催化剂活性相关联. 同时, 采用程序升温脱附技术对催化剂表面H2脱附性能进行了表征. 结果显 示, 碱土金属对催化剂活性的促进顺序为BaSrCa. 研究发现, 不同锆基碱土金属钙钛矿材料表面均具有较强的碱性位, 碱土金属的 加入影响了载体碱性强度以及金属-载体的相互作用, 其中BaZrO 可有效抑制H 的吸附. 因此, Ru/BaZrO 催化剂表现出优异的氨合 3 2 3 成活性. 关键词: 碱土金属; 钙钛矿; 锆; 钌催化剂; 氨合成 : 2012-07-26. : 2012-09-06. : 2013-02-20. *. : (05918102; : lin3jx@ : (2010D-5006-0502); (2007BAE08B02). Effect of alkali earth metals on performance of zirconium-based perovskite composite oxides supported ruthenium for ammonia synthesis WANG Ziqing, MA Yuncui, LIN Jianxin*, WANG Rong, WEI Kemei National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China Abstract: Zirconium-based perovskite materials with different alkaline earth metals were synthesized by the citric acid method and used as supports for ruthenium catalysts to catalytic ammonia synthesis reaction. The effects of alkaline earth metals on the texture properties, basic- ity, and catalytic activity were discussed. Additionally, the desorption properties of H2 on the surface of various catalysts were characterized by temperature-programmed desorption. The results showed that there were lots of strong basic sites appe