软硬段对聚氨酯弹性体结构性能的影响.pdfVIP

V ol . 23 N o . 2 160 Journal of Fu nct ional P oly m ers 20 10 6 区 洁 田立颖 王新灵 ( 上海交通大学化学化工学院 上海200240) : 采用本体聚合和溶液聚合两种方法 合成 一系列用聚乙二酸丁二醇酯二醇作为软段 的聚氨酯弹性体研究 硬段含量和聚醚添加量对聚氨酯弹性体综合性能的影响利用红外光 谱热分析力学性能测试记忆回弹性能和耐水解老化实验等测试手段对样品进行 表征与分析 结果表明: 硬段质量含量为31% ~ 35% 时 材料的力学性能较优 形状回复率可以达到7 5% ~ 85% ; 软段中聚醚添加量在4% ~ 5% ( 占软段的质量分数) 时 弹性体具有较好的力学性能和耐水 解性能 : 聚氨酯弹性体; 硬段; 软段; 结构性能; 微相分离 : O63 : A : 2010) Effect of Hard and Soft Segment on StructureProperty of Thermoplastic Polyurethane Elastomer OU J ie T IA N L iying WA N G X inling ( Schoo l of Chemist ry and Chemical Eng ineering Sh angh ai J iaot ong U niversit y Sh angh ai 200240 China) Abstract: A series of polyureth ane ( PU ) elast om ers b ased on po lybut y lene adipat e ( PBA ) as so ft seg m ent w ere synthesized by bulk polym er iz at ion and so lut ion polym er iz ation . T heir m orpho logies shap e memory ef fect t her mal st abilit y and mech anical prop erties w ere analyzed by m ean s of F TIR sp ect ra A FM T GA ten sile t est s and hydroly sis st abilit y testing. Po lyt et ramet hylene g lycol ( PT M G) w as added int o sof t seg ment to g et bet ter perf ormance o f t he specimen s. PU show s dif f erent perf orm ances by chang ing t he mol rat io o f M DI and BD ( h ar d seg ment ) and t he quant it y o f polyet her adding into the so ft seg m ent . R esult s show t h at bet t er mech anical prop er ties w ater resist ance and 75 % - 85% of shap e recov ery ar e obtained at 31% - 35% of h ard seg ment cont ent and 4 % - 5% of P T M G co nt ent . Key words: polyuret han