PVA-PVP-浸于GA-浸于KOH.pdfVIP

Polymer 51 (2010) 4850e4859 Contents lists available at ScienceDirect Polymer journal homepage: www.else /locate/polymer Alkaline solid polymer electrolyte membranes based on structurally modified PVA/PVP with improved alkali stability Jinli Qiao a, *, Jing Fu b, c, Rui Lin c, Jianxin Ma c, Jianshe Liu a a College of Environmental Science and Engineering, Donghua University, 2999 Ren’min North Road, Shanghai 201620, China b School of Resource and Environmental Engineering, East China University of Science and Technology, Melong Road 130, Shanghai 200237, China c Clean Energy Automotive Engineering Center, Tongji University, Caoan Road 4800, Shanghai 201804, China a r t i c l e i n f o a b s t r a c t Article history: Novel alkaline solid polymer electrolyte membranes that can conduct anions (OH) have been prepared Received 6 March 2010 from poly(vinyl alcohol)/poly(vinylpyrrolidone) (PVA/PVP) by blending and chemical cross-linking, fol- Received in revised form lowed by doping in aqueous KOH solution. The physicochemical properties of these membranes have 5 July 2010 been studied in detail by FTIR, TG, and SEM analyses. The ionic conductivity was found to be greatly Accepted 9 August 2010 dependent on the concentration of KOH and the interpenetrated PVP in the PVA matrix. A maximum Available online 14 August 2010 1