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DGT-induced copper flux predicts bioaccumulation and toxicity….pdf

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DGT-induced copper flux predicts bioaccumulation and toxicity…

University of Wollongong Research Online Faculty of Science - Papers (Archive) Faculty of Science, Medicine and Health 2012 DGT-induced copper flux predic s bioaccumula ion and ox ici y o bivalves in sedimen s with varying proper ies Stuart L. Simpson CSIRO, stuart.simpson@csiro.au Heloise Yverneau CSIRO National Graduate School of Chemistry of M ontp ellier A nne Cremazy University de Bo rdeaux, F rance Chad V. Jarolimek CSIRO Land and Water Helen Price University of Wollongo ng, hlp995@.au See next page for additional authors Publication Details Simpson, S. L., Yverneau, H., Cremazy, A ., Jarolimek, C. V., Price, H., Jolley, D. F. (2012). DGT-induced copper flux predicts bioaccumulation and toxicity to bivalves in sediments with varying properties. Environmental Science and Technology (Washington), 46 (16), 9038-9046. esearch Online is the open access institutional repository for the University of Wollongong. For further information contact the UOW Library: research-pubs@.au DGT-induced copper flux predic s bioaccumula ion and ox ici y o bivalves in sedimen s with varying proper ies Abstract Many regulatory frameworks for sediment quality assessment include consideration of contaminant bioavailability. However, the “snap-shots” of metal bioavailability provided by analyses of porewaters or acid- volatile sulfidesimultaneously extractable metal (AVS -SEM) relationships do not always contribute sufficient information. The use of inappropriate or inadequate information for assessing metal bioavailability in sediments may result in incorrect assessment decisions. The technique of diffusive gradients in thin films (DGT) enables the in situ measurement of metal concentrations in waters and fluxes from sediment porewaters.