C介孔TiO2复合材料的制备及其降解甲基橙的光催化活性研究.pdf

C/介孔TiO2 复合材料的制备及其降解甲基橙的光催化活性 沈晶晶，朱育丹，刘畅，陆小华* （南京工业大学材料化学工程国家重点实验室 210009） 摘要: 以介孔TiO2 为模板，葡萄糖为碳源，在500℃的N2 保护下合成了C/介孔TiO2 复合材料。采用X 射线衍射、低温 N2 物理吸附和热重等分析技术对样品进行了表征。结果分析表明，葡萄糖/介孔 TiO2 质量比为 0.2 时，热解生成的碳可弥 散分布于 TiO2 孔内外，比较均匀地修饰了介孔 TiO2 的内外表面，复合后仍保持锐钛矿相介孔结构。以甲基橙为目标降解 物，考察了样品的紫外光催化降解活性。结果发现，碳在短时间内提高了对甲基橙分子的吸附性能，从而为介孔TiO2 提供 高浓度的降解环境，体现了良好的协同效应。 关键词：葡萄糖；介孔TiO ；光催化；甲基橙 2 中图分类号：O643 文献标识码：A Preparation of C/Mesoporous TiO2 Composite and its Photocatalytic Degradation Activity on Methyl Orange SHEN Jingjing, ZHU Yudan, LIU Chang, LU Xiaohua* (State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China) Abstract: Using mesoporous TiO as template and glucose as carbon source,the preparation of C/mesoporous 2 TiO2 was accomplished at 500 ℃ with N2 deoxidizing atmosphere.The samples were characterized by X-ray diff- raction, N2 physical adsorption and thermogravimetry. It was found that when the mass ratio of glucose/ mesoporous TiO2 was 0.2, The carbon obtained by the pyrolysis dispersive distributed in the inside and outside of the pore, and modified the internal and external surface mesoporous TiO2. Composite was still anatase phase and kept mesopore structure.The photocatalytic activities were investigated by photodegrading the methyl orange.The result indicated that the carbon provided a environment for photocatalytic reaction in short time, so it improved the adsorption properties of methyl orange,and showed the good synergistic effect. Key words ：glucose; mesoporous TiO ;photocatalysis;methyl orange 2 *通讯联系人：陆小华 第一作者：沈晶晶 （1983—），女， Corresponding author: Prof. LU Xiaohua. E