锅炉炉前系统金属高温电化学特性分析研发.docVIP

锅炉炉前系统金属高温电化学特性研究 摘要 锅炉是一种能量转换装置，所以在其各个部位都会发生明显的温度变化。而长时间的温度的交替变化容易导致设备材料的老化和腐蚀。尤其是锅炉炉前部位，温度变化大，极易对材料造成损伤。而锅炉炉前系统的稳定直接关系到锅炉的正常运作。 本文采用电化学测量方法测定了锅炉炉前系统材料（321不锈钢、15CrMo）在高温条件及不同工作介质条件下的电化学特性，通过交流阻抗和塔菲尔曲线等手段探讨了其在高温条件下的电化学行为，研究其腐蚀特性。实验表明，锅炉炉前系统金属材料的耐蚀性能与温度、介质条件等因素密切相关。结果：----；结论： 关键词：炉前材料；交流阻抗；塔菲尔曲线；高温电化学；腐蚀 STUDY ON ELECTROCHEMICAL PROPERTIES OF METAL OF BOILER FURNACE SYSTEM AT HIGH TEMPERATURE ABSTRACT Boiler is a kind of energy conversion device, so there are significant temperature change in its various parts. Long time and alternating temperature easily lead to aging and corrosion of materials of equipment. Especially at boiler furnace system, large temperature variation, extremely damage the material.Therefore the stability of boiler furnace system relates directly to the normal operation of the boiler. 本文采用电化学测量方法测定了锅炉炉前系统材料（321不锈钢、15CrMo）在高温条件及不同工作介质条件下的电化学特性，通过交流阻抗和塔菲尔曲线等手段探讨了其在高温条件下的电化学行为，研究其腐蚀特性。实验表明，锅炉炉前系统金属材料的耐蚀性能与温度、介质条件等因素密切相关。 In this paper, materials(321 stainless steel, 15CrMo) have been measured by electrochemical method to study its electrochemical properties at high temperature condition and different medium conditions. Its electrochemical behavior at high temperature was studied by using the AC impedance and Tafel curve method, and analysis the corrosion characteristics. Experiments show that, the corrosion resistance of boiler furnace system metal material are closely related to temperature, medium conditions and other factors . Key words: material of boiler furnace system；AC impedance；Tafel curve；high-temperature electrochemistry Corrosion 目录 1 绪论.............................................................1 1.1 课题背景及目的..............................................1 1.2 不锈钢简介..................................................1 1.3 国内外研究状况..............................................2 1.4 课题研究方法................................................4 1.3.1 交流阻抗...............................................4 1.3.2 塔菲尔曲线.......