弱磁场下低温中和法制备亚微米非晶态δ-feooh的研究preparation.pdfVIP

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第21 期, 2173～2177 ACTA CHIMICA SINICA No. 21, 2173～2177 ·研究论文· 弱磁场下低温中和法制备亚微米非晶态 δ-FeOOH 的研究 傅小明* 钟云波 任忠鸣 邓 康 徐匡迪 (上海大学上海市现代冶金与材料制备重点实验室 上海 200072) 摘要 利用XRD 和SEM 分别对在弱磁场下通过低温中和法制备的羟基铁氧化物进行相成分和颗粒形貌分析. 试验结 果表明: 无磁场下, 产物是由部分球形和部分针状的α-FeOOH 组成. 0.1 T 磁场下, 产物是纺锤形的γ-FeOOH, 但是, 其 粒度分布很不均匀. 0.3 T 磁场下, 产物是球形的Fe1.833(OH)0.5O0.25. 0.5 T 磁场下, 产物是100 nm 左右的球形的非晶态 δ-FeOOH. Fe1.833(OH)0.5O0.25 是无磁场下制备的α-FeOOH 向弱磁场下制备的δ-FeOOH 转变的中间产物. 并且, 亚微米球 形Fe1.833(OH)0.5O0.25 和亚微米非晶态球形δ-FeOOH 的粒度分布都很均匀. 此外, 弱磁场影响羟基铁氧化物的结晶度. 关键词 弱磁场; 低温中和法; 亚微米; 非晶态δ-FeOOH Preparation of Sub-micron Amorphous δ-FeOOH by Low-temperature Neutralization Method in Low Magnetic Field FU, Xiao-Ming* ZHONG, Yun-Bo REN, Zhong-Ming DENG, Kang XU, Kuang-Di (Shanghai Key Laboratory of Modern Metallurgy Material Processing, Shanghai University, Shanghai 200072) Abstract Iron oxide hydroxide prepared by low-temperature neutralization reaction in zero and low magnetic field was analyzed with XRD and SEM. The experimental results turned out that spherical and acicular goethite (α-FeOOH) was prepared in zero magnetic field. Spindly lepidocrocite (γ-FeOOH) was prepared in 0.1 T magnetic field. And its grain size distribution was not homogeneous. Sub-micron spherical Fe1.833(OH)0.5O0.25 was prepared in 0.3 T magnetic field. Sub-micron spherical misawite (δ-FeOOH) of about 100 nm, the crystal- line state of which was amorphous, was prepared in 0.5 T magnetic field. Fe1.833(OH)0.5O0.25 was an intermedi- ate prod