材料科学基础-课件 清华skja_28精选.ppt

材料科学基础Fundamental of Materials §6.5 concentration dependence of D. Matano method Ⅰ.D-C dependence Ⅱ.Matano method §6.6 Kirkendall effect and Partial diffusion coefficients Ⅰ.K-experimental results: The markers move toward brass slice. Ⅲ.Partial diffusion coefficients. referred to the fixed interface Examples and Discussions Exercise * * Prof: Tian Min Bo Tel: E-mail: tmb@mail.tsinghua.edu.cn Department of Material Science and Engineering Tsinghua University. Beijing 100084 Lesson twenty-eight ＝ For points in C-x curve, t = const 利用边界方法 =0 Kirkendall–Smigelskas Ⅱ.K-effect: In substitutional solid solutions, the markers placed on original interface move parabolically with time toward the zinc-rich zone. This phenomenon is called K-effect The meaning of K-effect: Denied the diffusion mechanism about transposition Proved the vacancy mechanism Partial diffusion coefficients is different Built relationship between micro and macro Universality Accessary effect: Superfluous vacancy NA, NB : mole fraction 测l，记录t，可得到v，由实验曲线计算D， 由D、v，即可求得DA，DB