混凝土用高强高模量聚丙烯纤维的纺丝的研讨.pdf

混凝土用高强高模量聚丙烯纤维的纺丝的研究 卞荣兵”一，沈健2 摘要：本文介绍了高强高模量聚丙烯纤维的纺丝制备方法和加工工艺。研究了聚丙烯分子量、纺丝工艺、添加剂 对聚丙烯纤维性能的影响。结果表明高分子量聚丙烯纺出的纤维强度和衲始摸量高。亲水性马来酶酐接枝聚丙烯 可以提高纤维的亲水性能，纤维与水的接触角下降，可能是由于破坏了纤维的结晶，抗拉强度有所F降。添加有 效的抗氧剂防止在纺丝过程中的热分解，可以有效地提高聚丙烯纤维的强度和初始模量。针对混凝土的使月】场合， 纤维的高分散性是发挥纤维在混凝士中的功能的关键因素．而表面油剂是决定纤维分散性的关键因素。 关键词：高强度；高模量；聚丙烯纤维；混凝土；纺丝 researchof and Spinning high-strengthhigh-modulus fiberforconcrete polypropylene BIAN Jian2 Rong—bing’“2．SHEN ResearchInstitute 210008 (1 Science，Nanjing．Jiangsu Jiangsu ofBuilding 210093) 2PolymerDepartment．NamingUniversity,Nanjing．Jiangsu and of fiberwas inthis Fibermechanical AbsWact：SpinningprocessingtechnologypolypropylenepresentedpaPcL wereevaluatedand forvariablemolecular conditionsandadditives．Theresults properties compared weight，spinning have that molecular rawmaterialscouldbe with shown and higher weightpolypropylene spun highstrengthhigh modulus modifier,maleicgrafted thefiber fibers．Hydrophilie anhydridepolypropylene．canimprove hydrophilic reducedwater reducedtensile was because with contact thesao|etime，the propertyespecially angle．At strengthpossibly for effective thesemodifiersthe strtlcture anti—oxidantcanfurther disruptcrystalline