催化剂粒子在振荡流反应器中的悬浮分布+研究.pdfVIP

催化剂粒子在振荡流反应器中的悬浮分布 袁灿盛，吴嘉* (浙江大学化学工程与生物工程学系，杭州310027，中国) 摘要：配制不同粘度的硅油模拟液固催化反应的液相，借助可视化方法处理，得到了一定振幅和振荡频率 条件下不同粘度液相中催化剂粒子在振荡流反应器各个腔室的分布，得出各个腔室表征粒子浓度的β的值， 从β的值得到了判断粒子悬浮是否均匀的 k 值，并研究不同振荡频率对粒子悬浮分布的影响。结果表明只 要振幅和频率达到一定值，中高粘度下催化剂粒子在振荡流反应器中可以悬浮均匀。在一定的振幅下，随 着粘度的增大，要达到均匀悬浮状态，所需频率就越大。这些研究，填补了中高粘度介质下，振荡流反应 器中粒子悬浮定量研究的空白，为振荡流反应器在悬浮聚合反应工程的应用提供可靠的技术依据。 关键词：振荡流反应器；催化剂粒子；悬浮 The Suspension Distribution of Catalyst Particles in an Oscillatory Flow Reactor YUAN Cansheng ，WU Jia* Department of Chemical and Biochemical engineering, Zhejiang University ，Hangzhuo 310027 ，China Abstract ：We obtain the distribution of catalyst particles in each compartment in OFR with various liquid viscosity under a rage of oscillatory amplitudes and frequencies, on the base of visual experiments results. The value of β characterizing the particle concentration is acquired to get the value of k which is used to judge the uniformity of the catalyst particles. The results indicate that the catalyst particles can maintain in suspend uniformly in liquid with middle or high viscosity as long as the oscillatory amplitude and frequency reach a certain value. Under fixed amplitude the frequency in demand is raising with the increase of liquid viscosity to obtain uniform suspension. These results fill up the blank of quantitative research in particle suspension and provide reliable technical foundation to the application of suspension polymerization. Keywords ：oscillatory flow reactor ；catalyst particles ；suspension 振荡流反应器（Oscillatory Flow Reactor，简写作 OFR ）是一种新型的管式反应设备， 反应器内部的流通截面沿流动方向有规律地发生变化，将反应器的内部空间划分成串联形式 的多腔室结构。当反应物料流经反应器时，通过振荡机构在流体的平均流动上叠加一个轴向 的正弦振荡流动。振荡流动和多腔室结构的组合作用在流场中产生周期性的旋涡流动[1]，有 提交日期：2006-8-25 作者简介：袁