强磁场对透辉石光催化性能影响的实验本科.docVIP

强磁场对透辉石光催化性能影响的实验 Experiment of the diopside Processed by high magnetic field effection on the photocatalytic properties 摘 要 光催化技术具有反应条件温和、无污染、低能耗等特点，因而在环境保护、能源转换、新物质合成等方面具有广阔的应用前景。通过多种改性手段改善催化剂的活性，提高催化剂的光催化效率是将这一技术推向实际应用的重要环节。本文从固体废弃物再资源化、环境污染防治和半导体光催化材料制备的低成本化出发，提出将含钛高炉渣作为光催化材料进行综合利用的新方法。本文在综述半导体光催化材料的光催化机理及应用的基础上，利用处理过的透辉石作为光催化材料，研究光催化降解亚甲基蓝溶液的多种影响因素，以寻求含钛高炉渣综合利用的新途径。 实验所用光源为紫外灯，将透辉石作为光催化材料，悬浮于溶液中进行光催化反应。以亚甲基蓝降解率为评价指标，进行光催化降解的实验研究。 首先进行了透辉石作为光催化材料降解亚甲基蓝溶液的初步研究。结果表明：透辉石作为光催化材料降解亚甲基蓝溶液，降解率不是很高,为2.02%，说明透辉石的光催化性能不强。 其次进行了透辉石改性处理后作为光催化材料降解亚甲基蓝溶液的深入研究。利用XRD、SEM等多种测试手段。结果表明：适量掺杂TiO2，Fe2O3等均对亚甲基蓝溶液降解率有显著提高。磁场处理对透辉石降解亚甲基蓝溶液的光催化性能有所促进，其中磁场为6T时，掺杂0.34%TiO2与0.067%Fe2O3的透辉石降解效果较好，降解率为35.36% 关键词：透辉石；光催化；亚甲基蓝；降解率；强磁场Abstract Photocatalysis is an attractive approach for environmental protection, energy transformation and functional group transformation because of its advantage such as low-temperature, nonenergy intensity and non-pollution. Photocatalysts is the key part in photocatalysis, and further improvement on its activity and efficiency by selective surface treatment by modifying the properties of the particles is an essential step to apply this novel technology. At the present, a new method to apply titania-bearing blast furnace slag as the raw materials for making photocatalytec materials was proposed, aiming at an integrated utilization of resources and low-cost fabrication of semiconducting photocatalytic materials. Based on the review of photocatalytic mechanism and applications of photocatalysts, the diopside was used as photocatalytic materials to degrade MB solution through photocatalytic reactions. Effects of various factors on the degradation process were studied on the basis of experimental results. All of the present work is aimed at exploring diopside The photocatalytic reaction was progressed under the ultraviolet light (UV-light), while the TBBFS were suspended in the solutions. Photocatalytic actevity of diopside was evaluated by the degradation of