聚砜 双酚A聚硫酸中空纤维超滤膜的制备及性 能表征.pdfVIP

Material Sciences 材料科学, 2017, 7(9), 752-758 Published Online December 2017 in Hans. /journal/ms /10.12677/ms.2017.79098 Preparation and Characterization of Polysulfone/Bisphenol Sulfuric Acid Hollow Fiber Ultrafiltration Membranes Chen Zhang, Jiaxin Zhang, Ziqi Guan, Boyuan Zhou, Shenghui Liu, Min Liu* School of Materials Science and Engineering, East China University of Science and Technology, Shanghai nd th th Received: Nov. 22 , 2017; accepted: Dec. 4 , 2017; published: Dec. 14 , 2017 Abstract Polysulfone (PSf) and PSf/bisphenol sulfuric acid (BPA-PS) ultrafiltration hollow fiber membranes were successfully prepared by non-solvent induced phase separation (NIPS) and reverse thermal- ly induced phase separation (RTIPS) method. Pure water permeation flux, rejection rate, porosity, scanning electron microscopy, tensile test and pure water contact angle were performed to survey the permeation, morphology and mechanical properties. The results show that the phase separa- tion temperature of PSf/BAP-PS system increases and the viscosity decreases. The membrane structure presents a dense surface and a finger-like pores structure along its cross-section by us- ing the NIPS process. Meanwhile, the morphology of membranes takes on a porous surface and a spongy structure on its cross-section by using the RTIPS process. The mechanical properties of PSf/BAP-PS hollow fiber membranes are better than that of the membranes prepared with NIPS method. Keywords Polysulfone, Bisphenol Sulfuric Acid, Hollow Fiber Membrane, Ultrafiltration 聚砜/双酚A聚硫酸中空纤维超滤膜的制备及性 能表征 张 晨，张佳欣，关子奇，周博渊，刘圣慧，刘 敏* 华东理工大学，材料科学与工程学院，上海 *通讯作者。 文章引用: 张晨, 张佳欣, 关子奇, 周博渊, 刘圣慧, 刘敏.