以化学溶液法制备p型CuAlO2导电膜之制备及其特性之研究.DOCVIP

Fabrication of CuAl2O4 nanotube by electrospinning 1 Szu-Yu Su (蘇司羽), 2Te-Wei Chiu(邱德威) 1Student, Department of Materials and Mineral Resources Engineering, National Taipei University of Technology 2Professor, Department of Materials and Mineral Resources Engineering, National Taipei University of Technology 國立臺北科技大學材料科學與工程研究所 Abstract In our previous study, we synthesized CuCrO2 and CuCr2O4 nanofiber by electrospinning method[1, 2]. In this study we try to find the method to synthesized CuAl2O4 nanotube by electrospinning method. The electrospinning precursor Al2O3 was prepared by sol-gel method. The structure of the ?bers was characterized using X-ray diffraction, and the morphology of the ?bers was observed by ?eld-emission scanning electron microscopy. At begging the electrospinning ?ber was sintered at 650 °C to formed Al2O3 fiber. Then, Al2O3 nanofiber was soaked in ethylene glycol monomethyl ether with copper(II) nitrate trihydrate and Triton X-100 for deposit copper ions on the surface of Al2O3 nanofiber fiber. Soaked Al2O3 nanofiber was sintered at 1100°C in box furnace. Using alkaline solution and acid solution to wash out the impurity respectively. The CuAl2O4 nanotube with average diameter of about 200 nm were obtained. Keywords: CuAl2O4, nanotube, electrospinning.  Introduction Nanocrystalline copper aluminate (CuAl2O4) has high thermal stability, high mechanical resistance, hydrophobicity and low surface acidity. With above properties, it could be a good catalyst in decomposition of methane and dehydration of saturated alcohols to olefin, support of active metals, pigment or sensor material[3-6]…etc. Nanocrystalline copper aluminate able to be synthesized though sol-gel method[3], coprecipitation[7], hydrothermal synthesis[8].etc. Nanotube has unique properties and better performance than fiber, and also could be fabricated from different functional materials such as carbon, metal oxides. The metal oxide nanotube would have novel elec