两段式生物质的金属炭催化裂解的研究.doc

分类号 TQ 352.4 学位代码 308 密 级 GK 学校代码 10298学 号 南 京 林 业 大 学 论文题目： 作 者： 专 业：林产化学加工工程 研究方向：生物质能源与碳材料指导老师： 二一二年月 摘 要 以杉木屑为原料，采用式两段固定床反应器，下段炉用于杉木屑的热解，上段炉用于焦油的催化裂解，研究了催化剂小分子产物的催化裂解采用气相色谱在线分析裂解气体产物组分，使用气质联用技术分析冷却收集到的裂解液体产物组分，金属/炭催化剂的结构进行了分析表征。结果表明：木热分解小分子产物，乳糖、醛、酮以及愈创木酚类等含氧化合物，经过高温金属/炭基催化剂层后，裂解生成了富氢气体。其中，Ni/炭催化剂的催化效果最好。K/炭和Ca/炭催化剂对小分子产物中的重质组分具有较好的催化裂解效果，但是生成了较多的焦炭和水分。Fe/炭催化剂对焦油的轻质组分具有较好的催化裂解效果。但Mg/炭催化剂未见明显的催化效果。另外，Ni-Fe/木炭的催化效果没有Ni/炭催化剂的好。 关键词: 催化裂解木炭金属/C催化剂 Catalytie cracking of biomass using char-based catalyst in a two-stage Fixed-bedreaetor Abstract TWe used two vertical fixed bed reactor. The below section of furnace is used for sawdust pyrolysis. The top section of furnace is used for tar cracking. We research on one or more kinds of metal-based carbon, such as Ni、Ca、Mg、Fe, influencing on the changes of small molecule products of plant fiber cracking. We analyze and compare different types of metal catalysts influencing on biomass catalytic cracking. In the process of pyrolysis, the gaseous products were real time detected by gas chromatography, the liquid after cooling were analyzed by GC-MS, and the structure of metal-based carbon were analyzed by XRD. The results show that in the process of fir pyrolysis produced lactose, aldehydes, ketones, phenols, which are oxygenated compounds，when they passed the hot metal-based carbon, they are all cracked into rich-hydrogen gas. Among of catalysts, the Ni-carbon catalyst is the best, which crack a large of CH4, but also is good at cracking the light tar and heavy tar. K-carbon and Ca-carbon catalyst play the role on the cracking of light tar, but in the process of cracking, it generate a greater amout of coke and water. Fe-carbon catalyst play the role on the light tar. But Mg-carbon has no significant as catalyst. In addition, the Ni-Fe/carbon is less