三元乙丙橡胶的人工气候老化.pdfVIP

30 12 Vol. 30 No.12 2008 12 Journal of University of Science andTechnology Beijing Dec. 2008 1, 2) 1, 2) 1, 2) 赵泉林 李晓刚 高 瑾 1) , 100083 2) , 100083 ( EPDM ) , X ( XPS) ( SEM ) EPDM . : 90 d , EPDM 2m , C O C/ C OHC O O C O; ; , , , , EP DM , . ; ; ; ; T Q 3334 Artificial weathering of ethylenepropylenediene monomer (EPDM) rubber 1, 2) 1, 2) 1, 2) ZHAO Quanlin , LI X iaogang , GA OJin 1) School o M at erials Scien ce and Engineering , U niversity o S cience and T echnology Beijing , Beijing 100083, China 2) Beijing K ey Laborat ory or Corrosion, Erosion and Sur ace T echnology , Beijing 100083, China ABSTRACT T he e ects o arti icial w eathering on the chemical structure, sur ace topogr aphy and mechanical pro perties o et hylene propylenediene monomer ( EPDM ) w er e investig ated by Xray photoelectro n spectroscopy ( XPS ) , scanning electron microsco pe ( SEM ) , computercontr olled testing machine and spectrophotometer. T he results show ed that an ox idatio n layer o rmed a ter 90 d o ex posure. XPS results con irmed the production o C O C/ C OH, C O and O C O groups . With prolong ing ex posure t ime, the crosslink density incr eased linearly, t he sur ace o EPDM tur ned to redder, more yellow and lig hter. L ittle voids and micro cracks w ere ormed under ex posure to arti icial w eathering environment . T he tensile strengt h, tear str ength and hardness increased w ith prolo nging ex posure time. EY WORDS ethylenepr opylenediene monomer ( EPDM ) ; arti icial w eather ing ; chemical structure; sur ace topog raphy; me chanical propert ies ( EPDM ) ( CH 2