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salt mixtures III. Ternary univalent systems with common ion英文资料.pdf

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Dissociation model of the electrical conductivity of molten salt mixtures III . Ternary univalent systems with common ion a b a V . DANĚK , M . HURA , and M . CHRENKOVÁ d Institute of Inorganic Chemistry, Slovak Academy of Sciences, CS-842 36 Bratislava hDepartment of Inorganic Technology, Faculty of Chemical Technology, Slovak Technical University, CS-812 37 Bratislava Received 13 June 1989 Dedicated to Professor Ľ. Treindl, DrSc, in honour of his 60th birthday The dissociation model of the electrical conductivity of molten salt mixtures, based on the idea of an incomplete dissociation of electrolyte components was applied in some ternary univalent systems with a common anion as well as with a common cation . The systems of alkali halides , of alkali metal nitrates , and of silver halides were examined . It was found that in the systems with a common anion the dissociation degree increases with the increasing radius of the cation . In the systems with a common cation the dissociation degree increases with the decreasing radius of the anion . The dissociation model describes the course of the molar conductivity of ternary univalent systems with a common ion very well. The standard deviations of the experimental va