酸处理对纤维表面偶联剂吸附量的影响 Effect on Coupling Agent Adsorption of Basalt Fiber With Acid Treatment.pdfVIP

酸处理对纤维表面偶联剂吸附量的影响 李伟娜 申士杰 张莉 (北京林业大学材料与技术学院，北京100083) 文摘对玄武岩纤维表面进行酸刻蚀处理并浸泡铝锆偶联剂溶液，探讨酸浓度、酸处理时间和偶联剂浓 度对玄武岩纤维表面偶联剂吸附量的影响。通过FHR和xPS分另·1定性和定量地分析纤维表面官能团及C、 o、Si、zr元素的变化来表征纤维表面偶联剂的吸附量。结果表明：三因素对纤维表面偶联剂吸附量的影响程 度由大到小依次为酸浓度、偶联剂浓度和酸处理时间。随着酸浓度升高，纤维表面偶联剂吸附量呈现出先减小 后增大的趋势；酸处理时间延长和偶联剂浓度增大，纤维表面偶联剂的吸附量呈现逐渐增大的趋势。-3酸浓度 为3mol／L、处理1．5h、偶联剂浓度为3wt％时，偶联剂在玄武岩纤维表面的吸附量最大。 关键词酸处理，玄武岩纤维，铝锆偶联剂 Effecton ofBasaltFiberWithAcidTreatment CouplingAgentAdsorption LiWeinaShen Li ShijieZhang ofMaterialScienceand (College Technology，BeijingForestryUniversity，Beijing100083) AbstractWestudiedtheeffectofacid onbasaltfibersurface．Wethree etching designed tionof timeof acidandconcentrationof finishthiswork． hydrochloricacid，etchinghydrochloric couplingagent)to chemical andchemicalelements basaltfiberswere The C，O，Si，Zr)on analysised changes(functiongroups containing mRandXPS．Itisconcludedthatconcentrationof acidaffectedthe more by hydrochloric couplingagentadsorption increasementof acid ad- than timeand concentration．Withthe agent etching coupling hydrochloric on increasedfirstanddecreasedthen．AndwealsofoundthatzirconaluminatesCOU— fibersurface sorptionquantity increasedwiththe acidtreatmenttimeand absorption hydrochloric couplingagent hy— plingagent was valuesof drochlorica