镍基催化剂的制备及其对垃圾气化产氢的催化活性 Preparation of Ni-based catalysts and evaluation of their catalytic activity in gasification of municipal solid waste (MSW)to hydrogen.pdfVIP
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镍基催化剂的制备及其对垃圾气化产氢的催化活性 Preparation of Ni-based catalysts and evaluation of their catalytic activity in gasification of municipal solid waste (MSW)to hydrogen
Science
中国环境科学2009,29(4):391~396 ChinaEnvironmental
镍基催化剂的制备及其对垃圾气化产氢的催化活性
贺茂云,肖 波’,胡智泉,刘石明,郭献军(华中科技大学环境科学与工程学院,湖北武汉430074)
均匀分散在载体表面.并在下吸式固定床气化炉中,进行水蒸气催化气化城市生活垃圾有机组分的实验来评价镍基催化剂的催化活性.结果
程的产氢率远远高f气化过程,最高达19.9tool
H2/I嚯,低温段催化气化的潜在产氧率高于气化过程,但高温段低于气化过程:高温有利于气
率降至2%以F.而产气率则高j二气化过程.
关键词:氧化镍:镍基催化剂;陶粒;气化;垃圾
中图分类号:X705 文献标识码:A 文章编号:1000一6923(2009)04-0391-06
ofNi-based andevaluationoftheir in of soHdwaste
activity
Preparation catalysts catalytic gasificationmunicipal
(MSW)to Mao-yun,XIAOBo。,HUZhi—quan,LIUShi-ming,GUO of
hydrogen.HE Xiandun(School
Scienceand ofScienceand
University 430074,China).Ch/na
Engineering,Huazhong Technology,Wuhan
Science,2009,29(4):391-396
with
Abstract:Ni·basedwere ceramsiteascarrierthemethodof
catalystsprepared by impregnation,and
electronic
X—raydiffraction(XRD),X-rayfluorescence(XRF),BET,environmentalscanning
using
havea areaof
elemental surface
analysis.Ni—basedcatalystsspecific 101.3m2/g.nle
dispersiveX·ray(ESEM-EDX)and
active of were NiO coatedonthesurfaceof inameansize of
componentscatalystssphericalparticles supports range
in steam Was
about of oftheNi—based usedMSW
2pm.Furthermore,evaluationcatalyticactivity catalysts gasification
in
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