单晶硅的制绒及光电转化率的研究毕业论文.docVIP

（ 二 〇 一二 年 六 月摘要 提高单晶硅太阳能电池光电转换效率降低电池制作成本一直是人们研究热点。太阳能电池光电转换效率每提升1%其成本降低7%，可见提升光电转换效率的重要性。从单晶硅太阳能电池的发展来看人们主要把精力放在陷光结构的研究上而在众多陷光结构中硅表面织构是比较容易实现高效的，它可有效降低观反射率进而提高光吸收率，而且可使光倾斜入射进而增加入射光程，大幅提高太阳能电池的光吸收率。 本文主要采用KOH溶液和异丙醇对单晶硅片进行制绒。KOH溶液作为腐蚀溶液与单晶硅片反应，异丙醇作为表面活性剂主要起到清除硅表面反应后的氢气气泡使反应更好的进行。 影响单晶硅太阳能电池光电转换效率的重要因素之一就是硅片表面对光的吸收，腐蚀后的单晶硅片表面会出现倒金字塔形光线经过这些倒金字塔绒面至少有2次于硅面接触这样可大幅的减少光在硅片表面的反射。 影响单晶硅制绒因素有碱性溶液的浓度、制绒时间还有温度。本论文通过实验来找出单晶硅制绒的最佳条件。在不同碱溶液浓度、制绒时间、制绒温度条件下对单晶硅硅片进行制绒，制绒后在扫描电子显微镜下观察其表面形貌，使用漫反射积分系统测量其反射率，表面形貌较好，反射率较低的即为最佳制绒条件。 通过实验尝试得出制绒条件在KOH浓度为2.5%wt、制绒时间30min、制绒温度在84摄氏度的制绒参数下是效果最佳的。 关键词：单晶硅；太阳能电池；腐蚀；绒面；光转换效率。 Abstract Improve the photoelectric conversion efficiency of monocrystalline silicon solar cells to reduce battery production costs has been the research focus. The photoelectric conversion efficiency of solar cells per increase 1% 7% cost reduction can be seen to enhance the importance of the photoelectric conversion efficiency. People from the perspective of the development of the monocrystalline silicon solar cells is mainly focus on the light trapping structure in the number of light trapping structure of the silicon surface texture is easier to achieve efficient, it can effectively reduce the concept of reflectivity and thus increase the light absorption rate, but also make the light oblique incidence and thus increase the incident process, a substantial increase in light absorption rate of solar cells.  In this paper, using KOH solution and isopropyl alcohol on a monocrystalline silicon texturing. KOH solution as the etchant solution and the response of the monocrystalline silicon, isopropyl alcohol as a surfactant to play Clear silicon surface reactions of hydrogen bubbles so that the reaction to better carry out. An important factor affecting the photoelectric conversion efficiency of silicon solar cells is silicon surface light absorption, the monocrystalline silicon surface corrosion will appear inverted pyramid-shaped light inverted pyr