聚碳硅烷纤维的不熔化与SiC纤维制备研究.PDFVIP

SiC 29 SiC Research on Curing of Polycarbosilane Fiber and Preparation of SiC Fiber , , , (, 410073) C ENG Xiang-zhen, XIAO Jia-yu, XIE Zheng-fang, SONG Yong-cai (State Key Lab of Novel Ceramic Fibers Composites, National University of Defense Technology Changsha, 410073, China) : ( PDM S) , (PCS) , PCS , 190 PCS Si- , , - , SiC PCS Si PCS Si- O- Si , PCS Si- , SiC 3h, SiC 2.52GPa, SiC , : ; ; ; SiC : T Q343: A: 1001-4381 (2004) 01-0029-04 Abstract : The polycarbosilane (PCS) which is theprecursor of SiC fiber was synthesized in an auto- clave by thermal decomposition of polydimethylsilane PDMS( ) . PCS fiber was obtained by melt- . 190 , - , spinning The influence of curing timeat on the weight gain Si bond reaction degree gel content and oxygen content of PCS fiber was investigated The cured PCS fibers were then py-, . 1250 2 . rolyzed up to at a tube furnace in a N flow Theoxygen content and properties of SiCfibers were determined The results show that Si. - bond in the molecular structure of PCS reacts with . - - oxygen during the curing process Si O Si linked structures are therefore produced among PCS moleculars. The weight gain, Si- bond reaction degree, gel content, and oxygen content of PCS fiber increase with increase of the curing time. The oxygen content of SiC fiber increase gradually also. When the PCS fiber is cured for 3 hours and pyroly