高分子选论课件 开环聚合.pptVIP

* Ring - Opening Polymerization 1 Thermodynamic of ring-opening polymerization 1.1 General aspect n -R-Z- -[-R-Z-]- n comparison with polycondensation/addition polymerization and step/chain polymerization 1) polymerization rate (kinetic) equation similar to that of addition and chain polymerization 2) molecular weight of polymer ~ t curve similar to that of polycondensation and step 3) equilibrium of polymerization and depolymerization types of ring monomers: cyclic alkane -(-CH2-)- n=3, 4, 5… cyclic ether -(CH2-)-O- n=2, 3, 4… n=2 ethylene ox