高分子选论课件 共聚合.pptVIP

N1=（N21+N12）/2+N11=N12+N11 N2=（N21+N12）/2+N22=N12+N22 ∵ N0=N1+N2 令X1=N1/N0 X2=N2/N0 （克分子分数） ? ?H = (N1/N0)H11+(N2/N0)H22+(N12/N0)［H12+ H21-(H11+H22) ] = X1H11+X2H22+(N12/N0) [H12+H21-(H11+H22)] 令?=H12+H21-(H11+H22) 交互联结和自联结的聚合焓间差别 用条件概率P12或P21来表示N12 P12=k12[M1*][M2]/(k11[M1*][M1]+k12[M1*][M2])=1/(1+?1X)=1-P11 P21=1-P22=1/(1+?2X) X=[M1]/[M2] N12=N1P12=N0X1P12=N21=N0X2P21 ? ?H=X1H11+X2H22+X2P21 ?=X1H11+X2H22+X1P12 ? 无规共聚 P21 = X1 P12 = X2 交替┬ P21≠X1 P12≠X2 完全交替 P21=1 P12=1 P11=0 P22=0 嵌