高分子选论课件 聚合热力学.pptVIP

* Thermodynamics of Polymerization 1 Introduction 1.1 Process and Gibb?s free energy state 1 state 2 G1 G2 2nd Law four process in polymer science from thermodynamics 1) Melting of crystalline polymer PP, PA crystalline amorphous 2) Rubber elasticity + force - force tension 4~5, ?T~10 ℃, ?S= - (increase in order) 3) Mixing and miscibility polymer - solvent polymer - polymer MW determination polyblend MWD fractionation graft solution polymerization block coating and adhesion solution spinning