有机合成讲义REDUCTION1.pptVIP

Reduction I. Introduction Reduction in organic reaction: Removal of oxygen Addition of hydrogen Gain of electrons Hydrogenation : Hydrogenolysis: Three main pathways for reduction 1. The addition of electrons Electron source: Mg-Hg 2. The transference of hydride 3. The catalyzed addition of molecular hydrogen Other pathway: enzyme-catalyzed reduction The catalysts of hydrogenation i. Adams catalyst: PtO2 ii. Palladium : Pd-C, Pd(OH)2 iii. Raney nickel: iv. Copper chromite: CuCr2O4 v. Homogenous catalyst: The approximate order of reduction II. Hydrocarbons 1. Alkanes 2. Alkenes A