杨怡宽博士以聚乙烯醇薄膜支撑-东海大学机构典藏系统.pdf

私立東海大學化學工程與材料工程研究所 碩士論文 指導教授：楊怡寬 博士 以聚乙烯醇薄膜支撐液態薄膜萃取琥珀酸 Spearation of succinic acid through liquid membrane supported by PVA film 研究生：洪淯誠 撰 中華民國 105 年6月 摘要 本研究主要目的為以液態薄膜自琥珀酸水溶液中提取目的產物 琥珀酸；為了加強液態薄膜在操作上的穩定性，以支撐型液態薄膜為 發想，使用 聚乙烯醇(polyvinyl alcohol ，PVA)薄膜作為分隔板，除 了將液態膜定型外，另一方面也確保液態薄膜與發酵液各自隔絕不互 相影響。本研究大致分為三個部分：首先將進行縮甲醛反應以加強 PVA 薄膜耐用程度，調整不同甲醛溶液添加量來控制PVA縮甲醛程 度，也對 PVA 薄膜在成膜過程、厚度、膨潤度、催化劑以及造孔進行 討論。 第二部分則 以不同含量載體三正辛胺(trioctylamine ，TOA的液) 態薄膜分別對不同濃度之琥珀酸溶液做靜態飽和萃取實驗，探討彼此 相平衡關係。接下來則使用不同縮甲醛程度之 PVA 薄膜配合不同含量 載體之液態薄膜對模擬發酵液進行提取實驗；並以有別 於以往的夾持 方式組合操作對於琥珀酸進料濃度及液態薄膜的厚度做改變，探討琥 珀酸通量變化，藉由得到的平均總通量分析萃取琥珀酸時的阻力。 最後對液態薄膜搭配特定縮甲醛程度之PVA 薄膜時有良好通量 之特徵，以量測接觸角的方式探討液態薄膜與 PVA 薄膜間的親和性。 關鍵詞 ：琥珀酸、聚乙烯醇、甲醛、液態膜、三正辛胺 I Abstract The main purpose of this research is to extract the succinic acid by a liquid membrane from the aqueous solution. To strengthen the stability of the liquid membrane in operation, the system of supported liquid membrane is adpoted. And crosslinked polyvinyl alcohol film is used as a separator plate to ensure that the liquid membrane is isolated from the aqueous solution. This study is divided into three parts. The first part is focused on crosslinking of the PVA film by acid catalyzed formaldehyde to enhance the durability of the film. Different concentrations of formaldehyde solution were added to control the degree of crosslinking. Thickness, degree of swelling,the amount of catalyst addition and pore formation in the film forming process were discussed. The second part is about the study of phase equilibrium of the extractant phase and water phase. Different concentrations of TOA in the octanol were used to extraction succinic acid from