环氧基POSS对PLAPBAT共混材料发泡行为的影响.doc

环氧基POSS对PLA/PBAT共混材料发泡 行为的影响 刘伟何仕成张纯任粒周洪福 贵州理工学院材料与冶金工程学院北京工商大学中 通过熔融共混法制备了聚乳酸/聚己二酸对苯二甲酸丁二酯/聚倍半硅氧烷 (PLA/PBAT/POSS)复合材料，并利用超临界二氧化碳(C02)固相发泡法对复合 材料进行发沲，通过差示扫描量热仪、高级动态流变仪和扫描电子显微镜等对复 合材料的结晶行为、流变行为和发泡行为进行丫研究。结果表明，TOSS粒子对 基体树脂具有增塑效应，PLA的冷结晶温度降低，结晶度提高;复合体系的流变 性能明显提高，其发泡材料的泡孔密度和发泡倍率均随着POSS粒子含量的增加 而增大，当加入7份(质量份，下同)POSS时，发泡材料的泡孔密度提高至 8. 25X 107个/cm3,发泡倍率达到13倍;POSS粒子对PLA泡沬的泡孔形态具有显 著的调控作用。 关键词： 聚乳酸;聚己：：酸对苯.：甲酸丁：：酯;笼形聚倍半硅氧烷;发泡;复合体系; 2017-06-19 基金：国家自然科学基金 Effect of Epoxy-based POSS on Foaming Behavior of PLA/PBAT Blends LIU Wei HE Shicheng ZHANG Chun REN Li ZHOU Hongfu School of Materials and Metallurgical Engineering， Guizhou Institute of Technology; KevLaboratory of Processing and Quality Evaluation Technology of Green Plastics of China National Light Industry Council， Beijing Technology and Business University; Abstract： Poly (lactic acid) (PLA) /poly (butylencadipate-co-terephthalatc) (PBAT) /polyhedral oligomeric silsesquioxane (TOSS) composites and their foams were prepared by a melt-mixing method and a supercritical C02 solid state foaming method, respectively. Thermal behavior, rheological property, and foaming behavior of the composites were studied. The results confirmed the plasticization effect of POSS particles on the composites. The rheological results indicated that melt elasticity of the composites was improved with the addition of POSS. As a result, cellular structure of the composites foams was enhanced. Cell density and foaming expansion ratio of the composite foams increased with an increase of POSS content. The composite foams achieved a cell density of 8- 25X 10* cell/cm3 and an expansion ratio of 13 at the POSS content of 7 phr. POSS was found to have a positive effort on controlling the cellular structure of the composite foams. Keyword： poly (lactic acid) ; poly (butyleneadipate-co-terephthalate); polyhedral oligomeric silsesquioxane; foam; composite; Received： 2017-06-19 0前言 随着社会快速发展，研发高性能绿色高分子材料成为当前热点方向之一。其中， PLA与PBAT具有相似的加工性能和生物降解性，两者共混后可在较大