[理学]傅献彩物理化学Chapter 5 Chemical equilibrium.ppt

物理化学电子教案—第5章 Chapter 5 Chemical equilibrium Contents Chemical reactions Consider the reaction A+B ? C+D Chemical reaction system Fundamental equation Direction and limit of a chemical reaction Direction and limit of a chemical reaction Direction and limit of a chemical reaction Van’t Hoff equilibrium box Affinity of chemical reaction 5.2 For pg reactions aA ﹦bB Isothermal equation of chemical reaction The chemical potential of a real gases： Isothermal equation of chemical reaction The thermodynamic equilibrium constant Predict the direction of reaction Relation of constant and equation Empirical equilibrium constants Empirical equilibrium constants Empirical equilibrium constants Empirical equilibrium constants Different Forms of Equilibrium Constants Heterogeneous chemical reaction dissociation pressure The standard Gibbs function of formation The standard Gibbs function of reaction The standard Gibbs function of reaction The standard Gibbs function of reaction The standard Gibbs function of formation is very important How equilibrium responds to temperature. How equilibrium responds to temperature The isobaric equation of chemical reaction. Deduce the isobaric equation The T affects the chemical equilibrium The T affects the chemical equilibrium The T affects the chemical equilibrium The van’t Hoff equation The P affects the chemical equilibrium The P affects the chemical equilibrium The inert gas affects the chemical equi. 5.9 simultaneous equilibrium simultaneous equilibrium simultaneous equilibrium simultaneous equilibrium 5.10 Coupled Reactions Application of Coupled Reactions Thermodynamic data from K 5.11 Approximately Calculation Physical transitions Approximately Calculation JACOBUS HENRICUS VAN’T HOFF JACOBUS HENRICUS VAN’T HOFF JOHN DALTON JOHN DALTON （B,?,T） Define the Gibbs function of reaction and calculate it from tables of Gibbs function of formation. Calculate the equ