低温环保型聚丙烯酸酯乳液的合成及应用.pdfVIP

第 35 卷 第 5 期 染 整 技 术 Vol.35 No.5 2013 年 5 月 Textile Dyeing and Finishing Journal May 2013 低温环保型聚丙烯酸酯乳液的合成及应用 刘  旭，习智华 （西安工程大学 纺织与材料学院，陕西西安 710048） 摘 要 采用种子乳液聚合法合成低温环保型聚丙烯酸酯乳液粘合剂 , 即以丙烯酸丁酯（BA）、丙烯酸异辛酯 (EHA)、苯乙烯（ST）为软、硬单体，丙烯酸（AA）为功能单体，过硫酸钾为引发剂，HA 为交联单体，合成 了一种性能优良的聚丙烯酸酯涂料印花粘合剂。讨论了软硬单体配比、功能单体用量、交联单体用量及链转移 剂对乳液性能及涂料印花性能的影响。最终确定了乳液聚合最佳工艺条件：软 / 硬单体比为 1.218 8/1，功能单 体 AA 用量为 1.8%，交联单体 HA 用量为 2.6%，链转移剂硫醇用量为 0.52% 。合成粘合剂在涂料印花上应用时， 粘合剂用量为 30%，焙烘时间为 4 min。 关键词 环保；丙烯酸酯；自交联；粘合剂；涂料印花 中图分类号：TS 194.2 文献标识码：B 文章编号：1005-9350(2013)05-0044-04 The synthesis and application of low temperature environment friendly poly-acrylate emulsion LIU Xu, XI Zhi-hua ′ ′ （School of Textile and Materials, Xian Polytechnic University, Xi an 710048, China） Abstract The low temperature environment friendly poly-acrylate emulsion adhesive is prepared by seed emulsion polymerization method. It means that, with butyl acrylic (BA), ethylhexyl acrylate (EHA), styrene (St) as soft or hard monomer, acrylic acid (AA) as functional monomer, potassium persulfate as initiator, HA as crosslinking monomer, poly- acrylate adhesive provided with excellent performance for pigment printing is synthesized. The effects of the hard monomer to soft monomer ratio, dosage of functional monomer, dosage of crosslinking monomer and chain transfer agent on the emulsion performance and pigment printing property are discussed. Finally, the optimum process condition of emulsion polymerization is