[材料科学]磷酸盐体系中电参数对钛合金微弧氧化陶瓷膜组织的影响.doc

二 〇 一 〇 年 六 月 摘 要 　　微弧氧化是一项在有色金属表面生长陶瓷膜的新技术，利用该技术可在钛合金表面生成耐磨、耐蚀、耐高温以及电绝缘性能优异的陶瓷膜层。 微弧氧化(MAO)膜具有一系列优异特性，已得到人们的高度关注，其中尤以钛及其合金的MAO膜最受人们的重视。但MAO是一个多因素控制的复杂过程，不同的电学参数对氧化膜的特性影响很大，且其理论和实验研原位究还不全面、不充分。因此，在钛及其合金MAO膜的制备、表征及特性方面还有许多工作要做，所以，本论文利用微弧氧化技术，采用自制的微弧氧化在钛合金表面制备了含钙、磷的生物活性陶瓷涂层，研究了不同电学参数对涂层影响；用扫描电镜(SEM)测其表面形貌,并对现象及测试结果进行分析,从而推理其成膜机理。 研究结果表明，电解液组成为Na5P3O10 9.3g/L+Na2SiO3·9H2O 2g/L+Na2EDTA 2.0g/L，正/负向电压为380/160V，电源频率控制在800Hz在时，其厚度为19μm，在上述条件下微弧氧化15min在TC4钛合金上可形成完整的陶瓷层。 脉冲频率影响陶瓷层的表面质量，提高脉冲频率可获得平整均匀的陶瓷层表面，但减慢陶瓷层的生长速度。正向电压对陶瓷层厚度有较弱的线性影响，提高正向电压，陶瓷层的形成速度有所提高，均匀度相应提高；负向电压与层厚之间呈抛物线关系，提高负向电压可明显提高陶瓷层的厚度和均匀度，但其达到一定数值后，层厚的增加速度趋缓。 关键词：微弧氧化；电学参数；钛合金；生物活性陶瓷层 　　 Abstract 　　 Micro arc oxidation is a new technique，which can insitu form the ceramic coatings on the surfaces of Some non-ferrous metals.Insulting,wear,corrosion and heat resistant ceramic coatings can be obtained on surface of titanium alloys by microarc oxidation . MAO coatings have intensively attracted the attention of many Research groups due to its desirable characteristics，especially the coatings On the substrates of titanium and its alloys. MAO is a complicated process，which is controlled by multifactor，Different electrical Parameters，as-deposited MAO coatings show various properties.Moreover，the experimental and theoretical results are not systematic or complete.Therefore，further research work on preparation and characterization of MAO coatings on the substrates of titanium and its a1loys，which are extensively used in many various fields，is needed.Based on Micro-arc Oxidation technology,the coating of bioceramic that it has calcium phosphate compound was fabricated on the surface of titanium alloy substrate with the facility of Micro-arc Oxidation made by ourselves.The influence to the property of coating with different electrical parameters was investigated,Its surface morphologies were observed by SEM. The experimental phenomenon and the measured result was analyzed. The mechan