三聚氰胺分子印迹聚合物的合成与光谱学特性-南华大学学报.PDFVIP

24 2 () V ol. 24 No. 2 2010 6 Journal ofUn iver ity of South China( Sc ience and T echnology) Jun. 20 10 : 1673- 0062( 20 10) 02- 0094- 05 三聚氰胺分子印迹聚合物的合成与光谱学特性 肖静水, 梁 俊, 彭安国, 肖锡林, 王丽华, 刘慧君* ( , 421001) : 采用非共价印迹法, 以三聚氰胺为模 分子, 甲基丙烯酸为功能单体, 乙二醇 二甲基丙烯酸酯为交联剂, 合成了三聚氰胺分子印迹聚合物. 实验表明该印迹聚合物 对甲醇溶液中三聚氰胺具有良好的选择性结合能力, 对液态奶中的三聚氰胺的富集 率可达 98% 以上. 并结合紫外光谱及红外光谱对分子印迹聚合物的合成及结合机理 进行了初步解析. : 三聚氰胺; 液态奶; 印迹聚合物; 光谱学 : O657. 3; O623 : A Synthesisand SpectralChartacteristic ofMolecularly Imprinted Polymers forMelamine XIAO Jing-shu,i LIAN Jun, PEN An-guo, * XIAO X-i lin,WAN L-ihua, LIU Hui-jun ( School of Chem i try and Chem icalEng ineering, Univer ity of South China, H engyang, Hunan 421001, China) Abstract: M elam ine mi prin ted polym er particle w ere prepared by the copolym erization of m ethacry lic acid a m onom er and ethylene glycol dinethacry late a cro link ing agen t w herem elam inew a the mi prin tm olecu lar in pre ence of 2, 2c- azo - bi - i obutyron itrile a in itiator in m ethanol olution by non- covalent m olecu lar mi printing m ethod. The te t how ed that the mi printed polym er bead can preconcen trate m elam ine in m ethanol olu- tion w ith good electiv ity and the enrichm ent rate of m elam ine from liquid m ilk can reach 98% or above. The yn the i and binding m echan im ofm elam ine mi printed polym er w ere prelmi inary analy ed by the app lication of UV and in frared pectram ethod. Key words: M elam ine; L iqu id m ilk; Im printed polym er; Spectro copy (m elam ine) , , , ,