含氯化聚丙烯的吸油凝胶的制备与表征精选.docVIP

含氯化聚丙烯的吸油凝胶的制备与表征 摘要 随着世界工业的不断发展，油污排放日益增加，油品泄漏的途径和机会也就越来越多，特别是海上航运造成的大规模泄漏油事故。传统的吸油材料无论是性能还是产量上都不能满足当前的要求，而互穿网络吸油凝胶以其良好的吸油率、保油率和优异的再生利用性能等特点得到越来越多的重视。 本课题以氯化聚丙烯（CPP）和丙烯酸丁酯(BA)为原料，制备了半互穿网络型吸油凝胶。将氯化聚丙烯（CPP）共混在溶剂甲苯中，然后加入二乙烯基苯、丙烯酸丁酯，以偶氮二异丁氰结果ABSTRACT With the rapid development of the global industry, the greasy pollution is increasing day by day. Greasiness leakage, especially large scale oil leakage accident caused by marine shipping, is becoming more and more common. The traditional oil-absorbing materials can’t meet the requirements. But the oil gel with a structure of interpenetrating network is becoming more and more widely studied for its good oil-absorbing rate, oil retention rate and excellent recycled properties. This topic use chlorinated polypropylene (CPP) and butyl acrylate (BA) as ingredients to synthetize the oil-absorbing gel with a structure of semi interpenetrating network. We make the CPP dissolved in the toluene solvent, and then add o-divinylbenzene as crosslinker, butyl acrylate as monomer, and 2，2′-AzobisisobutyronitrileCPP, BA and crosslinker on the oil-absorbing properties of the gel were investigated. The results show that the oil-absorbing rate firstly increased and then tends to be stable with the increasing of BA. It has the highest oil absorption rate up to 7.9585g / g in the chloroform. The oil-absorbing rate firstly increased and then tends to be stable with the increasing of crosslinker content. It has the highest oil absorption rate up to 10.1646g / g in the chloroform. The oil-absorbing rate increases very fast in the first 5 hours and become saturated in the 12th hours. The oil-absorbing gel has a good recycle property, and it also keep an excellent oil-absorbing rate after 10 times used. KEY WORDS：olution polymerization, transfer network, oil absorption rate, chlorinated polypropylene 目录 第1章 前言 1 §1.1 高吸油树脂的研究背景 1 §1.1.1 油污来源及危害 1 §1.1.2 处理油污染的方法 2 §1.1.3 吸油材料 2 §1.2 高吸油树脂在国内外的发展概况 3 §1.3 高吸油树脂的分类及其聚合工艺 5 §