Synthesis of Zn compounds derived from H benzimidazol …由苯并咪唑衍生的化合物的合成.pdfVIP

Issue in Honor of Prof Rosalinda Contreras Theurel ARKIVOC 2008 (v) 172-186 Synthesis of Zn compounds derived from 1H-benzimidazol-2-ylmethanamine Antonio R. Tapia-Benavides,a Margarita Tlahuextl,a,* Hugo Tlahuext,b and Carlos Galán-Vidala aCentro de Investigaciones Químicas, Universidad A. del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km 4.5. U. Universitaria. CP 42184 Mineral de la Reforma, Hidalgo, México bCentro de Investigaciones Químicas, Universidad A. del Estado de Morelos, Av. Universidad 1001 Col., Chamilpa, CP 62100, Cuernavaca Morelos, México E-mail: tromero@.mx th Dedicated to Professor Rosalinda Contreras on the occasion of her 60 anniversary Abstract The influence of the pH on the synthesis of Zn(II) complexes derived from 1H-benzimidazol-2- ylmethanamine (HL) has been investigated with X-ray crystallography, FAB mass spectrometry, NMR, infrared and Raman spectroscopy. The crystal structures of (1H-benzimidazol-2- ylmethanamine)tetrachlorozincate(2-) dihydrogen [H LZnCl ] (2), (1H-benzimidazol-2- 3 4 3 ylmethanamine-κN )trichlorozincate(1-) hydrogen hydrate [H LZnCl ]•H O (3), (1H- 2 3 2 2 2 3 benzimidazol-2-ylmethanamine-κN ,N )dichlorozinc(II) [HLZnCl ] (4) and Bis[1H-