壬基水杨醛肟的合成及其铜萃 .doc

分类号 密级 U D C 编号 硕士学位论文  原 创 性 声 明 本人声明，所呈交的学位论文是本人在导师指导下进行的研究工作及取得的研究成果。尽我所知，除了论文中特别加以标注和致谢的地方外，论文中不包含其他人已经发表或撰写过的研究成果，也不包含为获得大学或其他单位的学位或证书而使用过的材料。与我共同工作的同志对本研究所作的贡献均已在论文中作了明确的说明。 作者签名： 日期： 年 月 日 关于学位论文使用授权说明 本人了解XX大学有关保留、使用学位论文的规定，即：学校有权保留学位论文，允许学位论文被查阅和借阅；学校可以公布学位论文的全部或部分内容，可以采用复印、缩印或其它手段保存学位论文；学校可根据国家或湖南省有关部门规定送交学位论文。 作者签名： 导师签名 日期： 年 月 日 摘 要 O/A=1：13min的情况下,自制铜萃取剂在有机相中体积分数为10%时，它对初始水相pH=2.0且Cu2+浓度为2.11g/L的模拟浸出液中铜的萃取率能达到非常高的98.58%，是一种对铜的萃取能力极强而反萃和铜铁选择性则一般的萃取剂。 通过添加水杨酸乙酯、苯甲酸乙酯、邻苯二甲酸二乙酯和己二酸二乙酯四种酯类改质剂对自制萃取剂进行改性。结果表明改质剂对萃取剂的铜铁选择性影响不大，反萃能力提高较明显。选择了水杨酸乙酯为改质剂，在水杨酸乙酯体积分数占有机相5%时，萃取剂的铜铁选择性系数为250，反萃率提高了8.36%达到92.88%。 关键词： ，，  ABSTRACT The copper resources is abundant in our country, but with the market demand for copper increasesd every year, the grade of the copper ore declined gradually, and more and more ore difficult to dealt with. All these problems lead to copper hydrometallurgy technology developed rapidly. In copper hydrometallurgy, extraction is a very important factor, but extractant also play an very important role in extraction process. So, copper extractant research and development is also increasingly attracting widespread attention. Though study of copper extractants early start in our country, the extractant which we developed species limited and cant meet the demand for many kinds of different leaching solution. At present, most of the copper extractant depend on imported in our country. In this paper ,The high performance copper extractant 5-nonyl salicylaldoxime was prepared from 4-nonylphenol，magnesium powderraformaldehyde，hydroxylamine sulfate and Sulfonated kerosene by one-pot synthesis. Analyzed and compared the difference of one-pot synthesis of and two-pot synthesis of 5-nonyl salicylaldoxime yield, found that one-pot synthesis of the product yield was higher than the two-pot synthesis of, and reduced op