pedot合成步骤.pdfVIP

POLYMERS FOR ADVANCED TECHNOLOGIES Polym. Adv. Technol. (2007) Published online in Wiley InterScience () DOI: 10.1002/pat.1003 Poly (3,4-ethylenedioxythiophene) g-Fe O polymer 2 3 composite–super paramagnetic behavior and variable range hopping 1D conduction mechanism–synthesis and characterization Kuldeep Singh, Anil Ohlan, Parveen Saini and S. K. Dhawan* Polymeric Soft Materials Section, National Physical Laboratory, New Delhi 110012, India Received 7 March 2007; Revised 21 August 2007; Accepted 21 August 2007 The present paper reports the preparation of poly (3,4-ethylenedioxythiophene) (PEDOT) ferri- magnetic conducting polymer composite by incorporation of ferrite particles in the polymer matrix by emulsion polymerization. Synthesis of PEDOT–g-Fe2O3 composite was carried out by chemical oxidative polymerization of EDOT with ferrite particles in the presence of dodecylbenzenesulfonic acid (DBSA) that works as dopant as well as surfactant in aqueous medium. The resulting conducting composite possesses saturation magnetization (Ms) value of 20.56 emu/g with a conductivity of 0.4 ScmS1, which was determined by VSM and four probe technique, respectively. B-H curve reveals that ferrimagnetic particles of g-Fe2O3 show super-paramagnetic behavior at room temperature which was also observed in PEDOT–g-Fe O composite. The resulting conducting ferrimagnetic 2 3 composite shows microwave absorption loss of 18.7–22.8 dB in the frequency range of 12.4–18 GHz. Thermogravimetric analysis of the composite revealed that the composite is thermally stable up to