树枝状聚酰胺_胺对O_W型模拟原油乳液的破乳性能.pdfVIP

( ) 2002 6 ACTA PET ROLEI SI ICA (PETROLEUM PROCESSI G SECTIO ) 18 3 : 2002 O/ W DEMULSIFICATION OF THE DENDRIMERS POLYAMIDOAMINE FOR THE SIMULATED CRUDE O/ W EMULSION 1, 2 2 2 1 王 俊 , 陈红侠 , 于翠艳, 杨锦宗 1 2 2 1 WA G Jun , CHE Hongxia , YU Cuiyan , YA G Jinzong (1 , 116012; 2 , 151400) ( 1The State Key Laboratory of Fine Chemical, Dalian University of Technology, Dalian, 116012, China; 2Dep t. of Petrochemical ngineering, Daqing Petroleum Institute, A nda 151400, China) : , , 10~ 30 ( PAMAM) IR PAMAM , O/ W PAMAM , , 10~ 30 PAMAM , 30 PAMAM 50 100 mg/ l , 5%O/ W 92% : ; ; ; ; : TE868 : A Abstract: A series of 1. 0~ 3. 0 G polyamidoamine ( PAMAM) were synthesized with divergent method under suitable conditions with ethylenediamine as core and methanolas solvent reacting alter natively with methyl acrylate and ethylenediamine. T he structure of PAMAM were characterized by IR and terminal analysis and the demulsification of PAMAM has been investigated by using the simu lated O/ W emulsion. The results showed that theoil phase could be separated rapidly from the emul sion and it was different from the conventional demulsifier. All the 1.0~ 3.0 G PAMAM can produce some effect on the emulsion. When the temperature was 50 and the 3. 0 G PAMAM concentration was 100 mg/ l, the dehydration rate of the simulated 5% O/ W emulsion has reached 92%. Key w rds: dendrimer; polyamidoamine; synthesis; simulated emulsion; demulsifier , 30, [ 1] , O/ W , O/ W [2] CW01 , , O/ W : : (