2_2_7_7_四碘_9_9_螺二芴的简便合成方法_英文_.pdfVIP

　第 19 卷 　第 3 期 感 光 科 学 与 光 化 学 Vol . 19 　No . 3 　 　200 1 年 8 月 PHO TO GRA PHIC SCIEN CE AND PHO TOCHEM ISTR Y Aug. ,200 1 　 研究快讯 A PRACTICAL METHOD TO SY NTHESIZE 2 ,2 ’,7 ,7 ’TETRAIODO9 ,9 ’SPIROBIFL UORENE WU Xiaoming , CHEN Xiaochuan , CAO Xiaoping , PAN Xinfu ( Dep art ment of Chem ist ry , N ational L aboratory of A pp lied Organic Chem ist ry , ) L anz hou University , L anz hou 730000 , P. R . Chi na Abstract : 2 , 2 ’, 7 , 7 ’tet raiodo9 , 9 ’spirobifluorene ( 2 ) is t he key intermediate of hole t ransport media and conducting polymer s. We developed a p ractical met hod by which 2 was highly selective synt hesized in good yield . Key words : 2 , 2 ’, 7 , 7 ’tet raiodo9 , 9 ’spirobifluorene ; sprain compound ; Sand meyer reaction Article ID : 1000323 1( 200 1) 030 16 104 　　CLC number : O644 　　Document code : A Conducting organic polymer s and macro organic molecule have att racted much recent scientific interest [ 13 ] , since t hey may play a key role in t he const ruction of modern elect ronic systems. 2 ,2 ’,7 ,7 ’tet rabromo9 ,9 ’spirobifluorene (1) [4 ] and 2 ,2 ’,7 ,7 ’tet raiodo9 ,9 ’ spirobifluorene (2) p rain compounds wit h a defined p hysical st ruct ure for use in synt he are s sizing hole t ransport media OMe TAD (3) and TAD (4) which have achieved imp ressive solar toelect rical energy conver sion efficiencies[5 ] . A solar cell based on OMe TAD convert s p ho tons to elec