[化学]Course 11+12 Gas Adsorption_ Desorption and Gas Storage Components in Shales.pptVIP

* * * * * * * * Utah, Colorado * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * Organic Matter on Gas Adsorption in Shale Modified from Helgeson et al., 2009 Type I Type II Type I contains more aliphatic and naphthenic groups relative to aromatic group. Does the difference in OM type affect gas adsorption in shale? Type II/III Gas Adsorption Capacity for Shales and Their Isolated Kerogen at 50°C Green River Shale Woodford Shale Langmuir Isotherm Equation Chemical equation for gas adsorption: S + M (g) = SM Vacant surface site Equilibrium constant: Because the number of filled surface sites (SM) is proportional to ?, the number of unfilled site (S) is proportional to (1- ?) , and the number of gas particles is proportional to gas pressure (P). The equation can be rewritten as Langmuir Isotherm Equation After rearranging Langmuir equation can be expressed as: ? = Langmuir equilibrium constant P = gas partial pressure ? = amount adsorbed, and ?max = maximum amount adsorbed Gas Adsorption Isotherm for Cameo Coal Langmuir maximum = 721 scf/tons kerogen Langmuir equilibrium constant: 35°C: 0.847 50°C: 0.516 65°C: 0.323 Effect of Kerogen Type on Langmuir Constant Cameo Coal (type III) Woodford Shale (type II) Green River Shale (type I) Comparison of Langmuir Constant of Shales to Their Isolated Kerogen Cameo Coal (type III) Woodford Shale (type II) Green River Shale (type I) Filled points = shale Open points = isolated kerogen Comparison of Langmuir Constant for Shales to Their Isolated Kerogen Cameo Coal (type III) Woodford Shale (type II) Green River Shale (type I) Type III Type II Type I Blakely Lee C-5-1 Oxy Tarrant #3 Relationship Between Langmuir Maximum and TOC Cameo Coal (type III) Woodford Shale (type II) Green River Shale (type I) Blakely Relationship Between Grain Density and TOC Cameo Coal (type III) Woodford Shale (type II) Green River Shale (type I) Blakely Gas Storage