两种不锈钢在模拟消声器环境中的电偶腐蚀行为.pdf

第35 卷 第3 期 中国腐蚀与防护学报 Vol.35 No.3 2015 年6 月 Journal of Chinese Society for Corrosion and Protection Jun. 2015 两种不锈钢在模拟消声器环境中的 电偶腐蚀行为 魏 强 李谋成 沈嘉年 上海大学材料研究所 上海 200072 摘要：采用氧化/冷凝液浸泡循环实验方法模拟汽车消声器内部环境，研究了409 和304 两种不锈钢在冷凝液中 的电偶腐蚀行为。结果表明，无氧化作用时两种不锈钢间电偶腐蚀效应较弱，304 钢对409 钢的加速腐蚀作用 很小。循环实验过程中，偶合电位较低时偶合电流密度往往较大。热氧化将明显增大两种不锈钢发生电偶腐 蚀的倾向性，但氧化温度为250 ℃时稳定偶合电流密度较小、电偶腐蚀效应不显著，而氧化温度为400 ℃时 409 钢在循环过程中将发生局部腐蚀，呈现出较大的偶合电流密度，电偶腐蚀效应较强。 关键字：汽车排气系统 消声器 不锈钢 电偶腐蚀 冷凝液腐蚀 中图分类号：TG 172 文献标识码：A 文章编号：1005-4537(2015)03-0233-06 Galvanic Corrosion Behavior of Two Stainless Steels in Simulated Muffler Environments WEI Qiang, LI Moucheng, SHEN Jianian Institute of Materials, Shanghai University, Shanghai 200072, China Abstract: The cyclic method of hot air oxidation/immersion in condensates was adopted to simu- late the internal service conditions of automotive mufflers. The galvanic corrosion between type 409 and 304 stainless steels was investigated during the condensates immersion by using electro- chemical measurements. The results of coupling potential and current indicate that the galvanic cor- rosion effect is very weak between these two steels without suffered from hot air oxidation. This means that 304 stainless steel can hardly accelerate the corrosion of 409 stainless steel as they con- tact directly in the condensate solutions. During the cyclic tests, the two steels show relatively high- er values for the coupling current in the low coupling potential cases. Hot air oxidation will en- hance the galva