同位素稀释热电离质谱法测定锡石U.pdfVIP

2016 年 11 月 地 球 学 报 Nov. 2016 第 37 卷 第 6 期: 779-783 Acta Geoscientica Sinica Vol.37 No.6: 779-783 www.地球学报.com 同位素稀释热电离质谱法测定锡石U-Pb 年龄探索 涂家润, 崔玉荣, 郝 爽, 李惠民, 周红英, 耿建珍 中国地质调查局天津地质矿产研究所, 天津 300170 摘 要: 针对我国锡多金属矿床的定年问题 , 建立一种采用同位素稀释热电离质谱 (ID-TIMS)法进行锡石 U-Pb 同位素定年的方法, 并与激光烧蚀电感耦合等离子体质谱(LA-ICP-MS)法进行对比验证。由于采用化 学处理技术分别纯化了 U 和 Pb, 减少了普通铅的影响, 大大提高了分析测定精度。将该方法应用于某地区 石英-锡石-黑钨矿脉的锡石样品分析, 获得了精确的 U-Pb 年龄值。 关键词: 锡石 ; U-Pb 同位素; 锡多金属矿床 ; 等时线; ID-TIMS; LA-ICP-MS 中图分类号: P578.47; P597 文献标志码: A doi: 10.3975/cagsb.2016.06.13 An Investigation of U-Pb Isotope Dating of Cassiterite with Isotope Dilution-thermal Ionization Mass Spectrometry TU Jia-run, CUI Yu-rong, HAO Shuang, LI Hui-min, ZHOU Hong-ying, GENG Jian-zhen Tianjin Institute of Geology and Mineral Resources, China Geological Survey, Tianjin 300170 S Abstract: Focusing on the problem of the dating of tin polymetallic deposits in China, the authors established a new method for U-Pb isotope dating of cassiterite with isotope dilution-thermal ionization mass spectrometry G (ID-TIMS), and made comparison with laser ablation inductively coupled plasma mass spectrometry. Because U and Pb are purified separately by the new experimental pretreatment technology, the influence of the common A lead is reduced, and the analytical precision is greatly improved. This method was applied to the cassiterite samples from a quartz-cassiterite-wolframite vein i