Process Model - Chemical Engineering：化工过程模型.ppt

* * * * * * * * * * * * * * * * * Energy Balance Equation (cont.) Case1: If msys, P and r are constant, we can write The above assumption may hold true for constant pressure liquid-system (r=constant) for which the input mass flow rate is equal to output mass flow rate (msys=constant) Applying eqn (15) in overall energy balance equation (12) (15) (16) Case2: msys varies with time; P and r are constant Energy Balance Equation (cont.) Case2: If msys is NOT constant but P and r are. Also, if the system is a lumped-parameter system For lumped-parameter system, because of the well-mixed assumption, we can define the properties of the fluid in the system to be equal to that of the outlet fluid stream, therefore (17) Energy Balance Equation (cont.) Applying eqn (17) in overall energy balance equation (12) From mass balance, we can also write, Substituting eqn (19) in (18), we get (18) (19) (20) Energy Balance Equation (cont.) Expanding eqn (20) Rearranging we get, For liquids, we can further simplify (21) (22) (23) Transient Energy Balance Example Constitutive Relationships Constitutive Relationships: Gas Law How many kilograms of hydrogen can be stored in the tank ? Hydrogen Storage For Fuel Cell Powered Vehicles Source of Pictures: /proceedings/ ToddSuckow-NHA-CaFCP-9-04.pdf Constitutive Relationships: Heat Transfer Rate of heat loss/gain by radiation ?   /hbase/thermo/bodcon.html Constitutive Relationships: Reaction Kinetics Picture Source: /pdf/mcg/petridishautumn2004.pdf Tissue Growth How is growth of tissues related to cell and media composition? Types of Variables State and Design Variables Input and Output Variables Manipulated (or Controlled) and Disturbance Variable * * * * * * * * * * * * * * * * * * * * * Prepared by Prof. K. Karan CHEE 222: CHEMICAL PROCESS DYNAMICS AND NUMERICAL METHODS Module-I: Introduction to Process Modeling Topics to be covered in this module General Introduction to Chemical Processing Process Mo