金属的后合成修饰.pptVIP

1. Introduction MOFs have recently emerged as an important family of porous materials due to their unique structural and functional properties. Some of these MOFs have already found applications in areas such as magnetism, catalysis, separations, and gas storage, placing them among the most interesting classes of solid-state materials. A key to accessing advanced MOF materials suitable for more specialized andsophisticated applications is to integrate functionalities of greater complexity into these materials. 2. PSM in proteins, carbon nanotubes, and porous silicates PTM of proteins ,covalent modi?cations that occur after translation and synthesis of a polypeptide. PSM of CNTs can be directed toward their end caps, defect-sites, and most importantly, sidewalls. E?orts on the PSM of microporous zeolites and the related zeolitic materials have been less abundant presumably due to their relatively small pore size and lack of accessible chemical functionality. Incontrast,PSM of mesoporous silicas,which possess much larger pores that are lined with reactive silanol (SiOH) groups, have been more extensively investigated. 3. Postsynthetic modi?cation of metal–organic frameworks 3.1 PSM of MOFs by non-covalent interactions 3.2 PSM of MOFs by coordinative interactions 3.3 PSM of MOFs by covalent bonds 3.4 Tandem PSM of MOFs 3.5 Protonation as PSM of MOFs 3.6 PSM of MOFs by doping with metals 3.1 non-covalent interactions The most common forms of postsynthetic non-covalent modi?cation of MOFs include guest removal, guest exchange,and ion exchange. 3.2 coordinative interactions In principle, there exist at least two di?erent approaches to PSM of MOFs with metal–ligand interactions. The ?rst targets the exposed metal sites of MOFs, whereas the second explores the coordination chemistry of the organic c