粒径大小对煤吸附甲烷量的影响推荐.doc

粒径大小对煤吸附甲烷的影响 张天军1, 许鸿杰1 ,任树鑫1 ,李树刚2 (1.西安科技大学 理学院，陕西 西安 ；2.西安科技大学 能源学院，陕西 西安 ) 范围为0.15~0.20mm、0.12~0.15mm、0.109~0.12mm、0.096~0.109mm、0.045~0.096mm的五种试样在Langmuir吸附理论和分子运动理论的基础上，推导出煤的吸附能、吸附位、比表面积及吸附量之间的关系；比表面积中图分类号：TD 712 文献标识码：AThe Effect of Particle Size on Adsorption of Methane on Coal ZHANG Tian-jun1, XU Hong-jie1, REN Shu-Xin1, LI Shu-gang2 （1. College of Sciences, Xian University of Science and Technology, Xian , China;2. College of Energy Science Engineering, Xian University of Science and Technology, Xian , China） Abstract: In order to research the effect of particle size on adsorption properties of coal, coal samples rich in gases are collected and five types of coal specimens are made. The grain diameters of these specimens are within the ranges of 0.15-0.20mm, 0.12-0.15mm, 0.109-0.12mm, 0.096-0.109mm, and 0.045-0.096mm, respectively. Under isothermal conditions, adsorption-of methane-on-coal tests are done for these specimens using the WY-98B adsorption constant determinator, and the law of how coals of different particle sizes adsorb methane is found. Based on the Langmuir adsorption theory and the molecular kinetic theory, relationships among coal’s adsorption energy, adsorption site, specific surface area, and quantity adsorbed are derived. The adsorption law is theoretically verified using these relationships and the theory of molecular structure characteristics. The verified adsorption law could be used to study the law of gas migration and gathering in coal seams, and the mechanism of coal and gas outbursts. Key words: Langmuir adsorption equation, specific surface area, adsorption site, adsorption energy.  煤是含有多种无机矿物杂质的多孔性介质,具有基质孔隙和天然裂隙双重结构。煤孔隙表面对瓦斯具有很强的吸附能力,瓦斯在煤层中的储集量依赖于孔隙体积以及孔表面积的大小等在Langmuir吸附理论及其分子运动理论的基础上，推导出了煤的吸附能、吸附位、比表面积及吸附量之间的关系；焦坪矿区崔家沟煤矿三种煤样的主要特征参数值如 表1 煤样的特征参数 Table 1 The parameters of coal 17.23 1.72 2.1 下峪口11#煤 24.60 1.29 2.4 崔家沟 7#煤 18.23 1.88 1.4 煤样通过研磨和采用分样筛分样的方法进行制备，把每一种煤样制成粒径范围为0.15~0.2mm、0.12~0.15mm、0.109~0.12mm、0.096~