文献阅读汇报3.pptVIP

英文文献阅读汇报 Precise determination of cadmium and lead isotopic compositions in river sediments Abstract separate Cd and Pb by using an anionic exchange chromatographic procedure Cd isotopic compositions: MC-ICP-MS; Pb isotopic ratios: TIMS factors: instrumental mass fractionation and isobaric interferences five Cd reference solutions and one Pb standard were repeatedly measured δ114/110Cd value:≤0.11‰ (2s); Pb isotopic ratios :≤0.5‰ (2s) Introduction the use of Cd and Pb isotopic compositions together can give a better understanding of metal pollution and their geochemical behavior. Pb isotopes will directly trace the sources of pollution and Cd isotopes can trace the anthropogenic fractionations. employed a one-stage anionic exchange procedure that both Cd and Pb can be separated from any other elements with a high recovery. Experimental SPEX Cd, SPEX-1 Cd, JMC Cd, Munster Cd and BAM-1020 Cd Seven sediment samples used in this study were collected at a depth of 0–10 cm from North River. North River is the important branch of the Pearl River, which was polluted by local industrial activities from its upstream. Samples 6 and 7 were collected in the vicinity of the Pb–Zn smelter. the key Laboratory of Isotope Geochronology and Geochemistry, Chinese Academy of Sciences. IsoProbeTM MC-ICPMS (GV instruments, Manchester, UK). a VG 354 TIMS (VG instruments, Manchester, UK). an anionic exchange chromatographic procedure to separate Cd and Pb from the matrix polyprep column was filled with 3mL of wet AG-MP-1M resin in this procedure This new kind of resin was macroporous and could produce high speed of anionic exchange. A PerkinElmer Sciex Elan 6000 ICP-MS (Waltham, MA, USA) Mass spectrometry standard-sample bracketing external normalization double spike techniques A Sn spectral interference occurs on two of the Cd isotopes measurements (112 and 114) and it was needed to be monitored and corrected Total procedural blank for Cd was determined by spiking the blank so