correlation between polymer molecular weight and optimal fullerene content in efficient polymer solar cells：（聚合物分子量和最佳的富勒烯含量之间的相关性高效聚合物太阳能电池）.pdfVIP

Organic Electronics 34 (2016) 229e236 Contents lists available at ScienceDirect Organic Electronics journal homepage: /locate/orgel Correlation between polymer molecular weight and optimal fullerene content in efficient polymer solar cells 1 1 * Jinan Gu , Jianyu Yuan , Wanli Ma Institute of Functional Nano Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials Devices, Soochow University, 199 Ren-Ai Road, Suzhou Industrial Park, Suzhou, Jiangsu 215123, PR China a r t i c l e i n f o a b s t r a c t Article history: In this contribution, a donor-acceptor (D-A) copolymer PTP8, consisting of alternating benzodithiophene Received 23 March 2016 and thienopyrroledione with conjugated side-chains on both donor and acceptor units, was sucessfully Received in revised form prepared. We further investigated the effect of polymer molecular weight on polymer physicochemical 7 April 2016 properties, solar cell device performance, polymer-PCBM blend morphology, and, most importantly, Accepted 8 April 2016 polymer/PCBM blend ratio. We found that increasing the molecular weight of the donor polymer can Available online 28 April 2016 both effectively improve the device performance and simultaneously stabilize solar cell efficiency over a wide range of polymer