degradation of naproxen by ferrous ion-activated hydrogen peroxide, persulfate and combined hydrogen peroxidepersulfate processes the effect of citric acid addition：（降解萘普生的亚铁ion-activated过氧化氢、过硫酸盐和氢结合peroxidepersulfate流程柠檬酸添加的效果）.pdfVIP

Chemical Engineering Journal 318 (2017) 254–263 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.else /locate/cej Degradation of naproxen by ferrous ion-activated hydrogen peroxide, persulfate and combined hydrogen peroxide/persulfate processes: The effect of citric acid addition Niina Dulova ⇑, Eneliis Kattel, Marina Trapido Department of Chemical Engineering, Tallinn University of Technology, Ehitajate tee 5, Tallinn 19086, Estonia h i g h l i g h t s Addition of CA showed promoting effect on NPX degradation by all systems at pH0 3. S O 2/Fe2+/CA proved the most effective in NPX degradation at a wide range of pH. 2 8 Non-purgeable organic carbon was degraded gradually during the NPX mineralization. 2 HO was proposed as the predominant radical in activated H O /S O systems. 2 2 2 8 NPX transformation products were identified in all CA-Fe2+-activated systems. a r t i c l e i n f o a b s t r a c t Article history: Naproxen (NPX), a widely used non-steroidal anti-inflammatory drug, has been detected extensively in Available online 4 July 2016 different environmental systems at concentrations ranging from ng/L to lg/L, which may have a detri- mental effect on human health and natural ecosystems. In this study, the degradation of NPX by citric Keywords: acid (CA) chelated ferrous ion-activated hydr