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Fabrication of carbon nanotubes-材料合成化学课件PPT
Introduction Fabrication of carbon nanotubes Conclusion The cost of CVD is lower than the others. CNTs can grow on desired substrate. The efficiency and yield is higher. * Carbon Nanotubes Outline Arc charge Laser ablation Chemical vapor deposition (CVD) 0.2 steel ~0.2 Kevlar ~ 1 CNTs Youngs modulus (TPa) Material CNTs: carbon nanotubes, SWNTs: single-walled nanotubes 1. The electrical current density of CNTs is 1000 times greater than copper . 2. Thermal conductivity of CNTs, 3500 W/(m·K), is higher than copper , 385 W/(m·K). 3. Temperature stability of CNTs is 2800℃ in vacuum and 700 ℃ in air. 4. The area of SWNTs , 1g, reaches 8000 m2. …… The property of CNT is superior to other materials! Introduction Potential Application Wikipedia s CNTs structural Electro- magnetic Chemical Mechanical Electro- acoustic combat jacket solar cells hydrogen storage loudspeaker thermal radiation Mechanism catalyst CNT graphite powder catalysts CNT arc discharge Certain Atmosphere Arc discharge U (DC 10-35V) - + graphite graphite CNTs cross section CNTs shell deposits D=~1mm cooled Co Ni Y Fe Analytical Letters, 2003, 36(15), 3119-3145. 20-100 mg/h, even 1.2 g/h Arc discharge 1. Nature,1991, 354, 56-58. 2. Nature, 1992, 358, 220-222. Arc discharge The yield is about 30%-50% , can be limited by the anode and several other factors. Nature, 1997, 388, 756-758. SWNTs Arc discharge Diamond and related materials, 2002,11, 914-917. furnace laser Graphite target copper rode Water cool CNTs Graphite target Laser CNTs Inert gas Laser ablation Wikipedia Single-walled carbon nanotubes (SWNT) Laser ablation Analytical Letters, 2003, 36(15), 3119-3145. Laser ablation The improvement : the addition of a second pulse furnace laser2 Graphite target copper rode Water cool CNTs laser1 Analytical Letters, 2003, 36(15), 3119-3145. Co/Ni Laser ablation Free electron laser (FEL) (1.5g/h) Nano Letters, 2002, 2(6), 561-566. The method is pri
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